Carbon nanotubes-coated cement particles for cement-based sensors with excellent piezoresistivity

Typically, self-sensing cement composites are prepared by directly mixing cement particles with conductive additives, such as carbon black, carbon nanotubes (CNT), and graphene. This study proposes a novel approach to directly coat cement particles with CNT as the conductive filler (CNT@cement) before contact with water, aiming to develop a high-performance self-sensing cement-based sensor. CNT@cement nano/micro hybrid fabrication relies on a simple and efficient method that enables the uniform absorption of CNT on the surface of cement particles without any surfactants, thereby not diminishing the workability and mechanical properties of cement composites. This cement composite exhibits improved microstructure, bending strength, and electrical conductivity. Remarkably, the formulation with the addition of 0.1 wt% CNT@cement hybrid increases the bending strength by about 23% and improves the electrical conductivity by approximately two orders of magnitude, outperforming previously reported cement composites with similar CNT content. Additionally, outstanding piezoresistivity with a fractional change in resistivity of 1.26 is achieved for our cement-based sensor. These findings represent a major step toward the practical application of CNT in structural health monitoring.