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Rehydration of katoite as a layered double hydroxide: an in situ study

Autor(en): ORCID
ORCID
ORCID
ORCID
ORCID
ORCID
Medium: Fachartikel
Sprache(n): Englisch
Veröffentlicht in: RILEM Technical Letters, , v. 6
Seite(n): 8-16
DOI: 10.21809/rilemtechlett.2021.130
Abstrakt:

Calcium aluminate layered double hydroxides (Ca-Al LDHs) constitute a considerable part of cementitious waste fines. Although cementitious waste fines have proven to be recyclable by thermal treatment at moderate temperatures (400–700 °C), understanding how each phase rehydrates and contributes to the binding properties of rehydrated cementitious materials is still necessary. In this study, the de(re)hydration of katoite is investigated through in situ techniques, and its applicability as an alternative cement or supplementary cementitious material (SCM) is discussed. The research employed X-ray diffraction, isothermal calorimetry, in situ wide-angle X-ray scattering (WAXS), and rotational/oscillatory rheometry. Katoite synthesized by a mechanochemical process was dehydrated at 400 °C, producing mainly mayenite. During rehydration, calorimetry presents high heat production in the first minutes. WAXS shows prompt recovery of katoite and increasing formation of monocarboaluminate (Ca-Al LDH) after 30 s of rehydration. The findings confirm the direct association between rapid heat release and phase reformation. Rehydrated pastes present a high yield stress and an increasing storage modulus, indicating rapid binding properties. The consolidation is also correlated with cumulative heat and monocarboaluminate formation. The results indicate the potential of calcined katoite for use as rapid set alternative cement or SCM.

Copyright: © 2021 Antonia Alana Lima Pacheco, Thiago Ricardo Santos Nobre, Marcel Hark Maciel, Celso Valentim Santilli, Antonio Carlos Vieira Coelho, Sérgio Cirelli Angulo
Lizenz:

Dieses Werk wurde unter der Creative-Commons-Lizenz Namensnennung 4.0 International (CC-BY 4.0) veröffentlicht und darf unter den Lizenzbedinungen vervielfältigt, verbreitet, öffentlich zugänglich gemacht, sowie abgewandelt und bearbeitet werden. Dabei muss der Urheber bzw. Rechteinhaber genannt und die Lizenzbedingungen eingehalten werden.

  • Über diese
    Datenseite
  • Reference-ID
    10603690
  • Veröffentlicht am:
    17.04.2021
  • Geändert am:
    02.06.2021
 
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