Cross-linked self-healing polymers containing rosin moiety based on dynamic urea and multiple hydrogen bonds
Autor(en): |
Liwei Lu
caili yu zhongqun zhou faai zhang |
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Medium: | Fachartikel |
Sprache(n): | Englisch |
Veröffentlicht in: | Smart Materials and Structures, 21 April 2023, n. 6, v. 32 |
Seite(n): | 065021 |
DOI: | 10.1088/1361-665x/acd505 |
Abstrakt: |
In recent years, the use of renewable biomass resources to prepare self-healing polymers has become a hot research topic because of the shortage of fossil resources. Herein, a novel type of rosin-based cross-linked polymer (PR) with dynamic urea and multiple hydrogen bonds is fabricated by copolymerizing a rosin ester with a dynamic crosslinking agent poly(urethane-urea) through a simple UV-initiated reaction. Owing to its robustly dynamic bonds, the resulting PR has both good mechanical properties and ideal self-healing ability. Specifically, the PR with 25.4% biomass rosin reaches a tensile strength of up to 4.1 MPa, an elongation at break of 112%, and stress self-healing efficiency of 91.3% at 80 °C for 24 h. Remarkably, the PR with a glass transition temperature above room temperature exhibits good shape memory behavior and excellent weldability (afford 2500 g after healing at 80 °C for 5 h). Finally, by surface platinum spraying and pre-stretching treatment, strain sensors based on microcracking mechanisms are realized. |
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Datenseite - Reference-ID
10724759 - Veröffentlicht am:
30.05.2023 - Geändert am:
30.05.2023